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gPREPARING DUCTILE COPPER BASED

BULK METALLIC GLASSES

IN APPLICATION ENABLED SHAPES

FOR TARGETED INDUSTRIESh

This project advances new applications for copper. Bulk metallic glasses (BMGs) have been developed by us and others since the 1990s by designing complex multi-component alloys that can be easily vitrified from the melt. These alloys have low melting temperatures near 850C and shaping temperatures in the glassy state (near Tg)  near 500C thus reducing energy consumption and allowing low cost net-shape precision manufacturing of sheet, disks, wires, foams (porous bulk materials) and others. 

Due to their 2% elastic strain range (as compared to 0.2% for crystalline materials) BMGs currently have the best known values for the performance index 2/E (where and E are respectively the yield strength and Youngfs modulus).

These properties open a variety of applications as springs (such as vehicle engine valve springs), pressure gauges, suspensions, slat tracks for aircraft wings, micro-gears, reinforcement of sporting goods, cell-phone casings, bullet proof jacket linings, tools especially in biomedical industry and many others.

Previously discovered BMGs often contained several percent of copper but their development nevertheless already contributes a small new demand for pure copper because BMGs are most often prepared by casting into massive copper moulds.

However, the members of the present project have recently discovered a new class of Cu-based bulk metallic glasses with copper content in the 60-65% range. These Copper-based BMGs show 2 GPa strength and extensive room-temperature ductility up to 50% strain without fracture. No other metallic material has ever shown such extensive room temperature plasticity at such yield strength levels.

According to the latest studies, demand for BMGs in general could rise to about 40,000 tons/yr in the next ten years. Since these alloys generally contain about 20% copper, this would lead to some 8,000 tons/yr of new demand for high purity copper. However, if as this project aims at, the new families of copper-rich BMGs can be further developed and made available for testing by interested industrial players, it is possible that they will catch part of this market. In that case the numbers will be closer to 15 to 20 kilo-tons/yr of copper without consideration of the surge in demand for pure copper for the manufacturing of the casting moulds.

 

 

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